dc.date.accessioned | 2023-02-09T18:15:47Z | |
dc.date.available | 2023-02-09T18:15:47Z | |
dc.date.created | 2022-09-02T14:47:24Z | |
dc.date.issued | 2022 | |
dc.identifier.citation | Aslyamov, Timur Janssen, Mathijs Adriaan . Analytical solution to the Poisson–Nernst–Planck equations for the charging of a long electrolyte-filled slit pore. Electrochimica Acta. 2022, 424 | |
dc.identifier.uri | http://hdl.handle.net/10852/99855 | |
dc.description.abstract | We study the charging dynamics of a long electrolyte-filled slit pore in response to a suddenly applied potential. In particular, we analytically solve the Poisson–Nernst–Planck (PNP) equations for a pore for which λD≪H≪L, with λD the Debye length and H and L the pore’s width and length. For small applied potentials, we find the time-dependent potential drop between the pore’s surface and its center to be in complete agreement with a prediction of the celebrated transmission line model. For moderate to high applied potentials, prior numerical work showed that charging slows down at late times; Our analytical model reproduces and explains such biexponential charge buildup. | |
dc.language | EN | |
dc.rights | Attribution 4.0 International | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.title | Analytical solution to the Poisson–Nernst–Planck equations for the charging of a long electrolyte-filled slit pore | |
dc.title.alternative | ENEngelskEnglishAnalytical solution to the Poisson–Nernst–Planck equations for the charging of a long electrolyte-filled slit pore | |
dc.type | Journal article | |
dc.creator.author | Aslyamov, Timur | |
dc.creator.author | Janssen, Mathijs Adriaan | |
cristin.unitcode | 185,15,13,15 | |
cristin.unitname | Mekanikk | |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 2 | |
dc.identifier.cristin | 2048372 | |
dc.identifier.bibliographiccitation | info:ofi/fmt:kev:mtx:ctx&ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Electrochimica Acta&rft.volume=424&rft.spage=&rft.date=2022 | |
dc.identifier.jtitle | Electrochimica Acta | |
dc.identifier.volume | 424 | |
dc.identifier.pagecount | 0 | |
dc.identifier.doi | https://doi.org/10.1016/j.electacta.2022.140555 | |
dc.type.document | Tidsskriftartikkel | |
dc.type.peerreviewed | Peer reviewed | |
dc.source.issn | 0013-4686 | |
dc.type.version | PublishedVersion | |
cristin.articleid | 140555 | |