dc.date.accessioned | 2022-03-26T16:15:48Z | |
dc.date.available | 2022-03-26T16:15:48Z | |
dc.date.created | 2022-02-10T13:51:04Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Piel, Felix Müller, Markus Winkler, Klaus Skytte Af Sätra, Jenny Marie Wisthaler, Armin . Introducing the extended volatility range proton-Transfer-reaction mass spectrometer (EVR PTR-MS). Atmospheric Measurement Techniques. 2021, 14(2), 1355-1363 | |
dc.identifier.uri | http://hdl.handle.net/10852/92962 | |
dc.description.abstract | Proton-transfer-reaction mass spectrometry (PTR-MS) is widely used in atmospheric sciences for measuring volatile organic compounds in real time. In the most widely used type of PTR-MS instruments, air is directly introduced into a chemical ionization reactor via an inlet capillary system. The reactor has a volumetric exchange time of ∼0.1 s, enabling PTR-MS analyzers to measure at a frequency of 10 Hz. The time response does, however, deteriorate if low-volatility analytes interact with surfaces in the inlet or in the instrument. Herein, we present the extended volatility range (EVR) PTR-MS instrument which mitigates this issue. In the EVR configuration, inlet capillaries are made of passivated stainless steel, and all wetted metal parts in the chemical ionization reactor are surface-passivated with a functionalized hydrogenated amorphous silicon coating. Heating the entire setup (up to 120 ∘C) further improves the time-response performance.
We carried out time-response performance tests on a set of 29 analytes having saturation mass concentrations C0 in the range between 10−3 and 105 µg m−3. The 1/e-signal decay times after instant removal of the analyte from the sampling flow were between 0.2 and 90 s for gaseous analytes. We also tested the EVR PTR-MS instrument in combination with the chemical analysis of aerosols online (CHARON) particle inlet, and 1/e-signal decay times were in the range between 5 and 35 s for particulate analytes. We show on a set of example compounds that the time-response performance of the EVR PTR-MS instrument is comparable to that of the fastest flow tube chemical ionization mass spectrometers that are currently in use. The fast time response can be used for rapid (∼1 min equilibration time) switching between gas and particle measurements. The CHARON EVR PTR-MS instrument can thus be used for real-time monitoring of both gaseous and particulate organics in the atmosphere. Finally, we show that the CHARON EVR PTR-MS instrument also rapidly detects highly oxygenated species (with up to eight oxygen atoms) in particles formed by limonene ozonolysis. | |
dc.language | EN | |
dc.publisher | Copernicus GmbH | |
dc.rights | Attribution 4.0 International | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.title | Introducing the extended volatility range proton-Transfer-reaction mass spectrometer (EVR PTR-MS) | |
dc.type | Journal article | |
dc.creator.author | Piel, Felix | |
dc.creator.author | Müller, Markus | |
dc.creator.author | Winkler, Klaus | |
dc.creator.author | Skytte Af Sätra, Jenny Marie | |
dc.creator.author | Wisthaler, Armin | |
cristin.unitcode | 185,15,12,0 | |
cristin.unitname | Kjemisk institutt | |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 1 | |
dc.identifier.cristin | 2000003 | |
dc.identifier.bibliographiccitation | info:ofi/fmt:kev:mtx:ctx&ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Atmospheric Measurement Techniques&rft.volume=14&rft.spage=1355&rft.date=2021 | |
dc.identifier.jtitle | Atmospheric Measurement Techniques | |
dc.identifier.volume | 14 | |
dc.identifier.issue | 2 | |
dc.identifier.startpage | 1355 | |
dc.identifier.endpage | 1363 | |
dc.identifier.doi | https://doi.org/10.5194/amt-14-1355-2021 | |
dc.identifier.urn | URN:NBN:no-95554 | |
dc.type.document | Tidsskriftartikkel | |
dc.type.peerreviewed | Peer reviewed | |
dc.source.issn | 1867-1381 | |
dc.identifier.fulltext | Fulltext https://www.duo.uio.no/bitstream/handle/10852/92962/1/amt-14-1355-2021.pdf | |
dc.type.version | PublishedVersion | |
dc.relation.project | EC/H2020/674911 | |
dc.relation.project | EC/H2020/65410 | |