dc.date.accessioned | 2022-03-19T18:19:47Z | |
dc.date.available | 2022-03-19T18:19:47Z | |
dc.date.created | 2021-08-31T10:27:35Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Glessi, Cristiano Mahgoub, Aya Hagen, Cornelis W. Tilset, Mats . Gold(I) N-heterocyclic carbene precursors for focused electron beam-induced deposition. Beilstein Journal of Nanotechnology. 2021, 12, 257-269 | |
dc.identifier.uri | http://hdl.handle.net/10852/92656 | |
dc.description.abstract | Seven gold(I) N-heterocyclic carbene (NHC) complexes were synthesized, characterized, and identified as suitable precursors for focused electron beam-induced deposition (FEBID). Several variations on the core Au(NHC)X moiety were introduced, that is, variations of the NHC ring (imidazole or triazole), of the alkyl N-substituents (Me, Et, or iPr), and of the ancillary ligand X (Cl, Br, I, or CF 3 ). The seven complexes were tested as FEBID precursors in an on-substrate custom setup. The effect of the substitutions on deposit composition and growth rate indicates that the most suitable organic ligand for the gold precursor is triazole-based, with the best deposit composition of 15 atom % gold, while the most suitable anionic ligand is the trifluoromethyl group, leading to a growth rate of 1 × 10 −2 nm 3 /e − . | |
dc.language | EN | |
dc.publisher | Beilstein-Institut | |
dc.rights | Attribution 4.0 International | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.title | Gold(I) N-heterocyclic carbene precursors for focused electron beam-induced deposition | |
dc.type | Journal article | |
dc.creator.author | Glessi, Cristiano | |
dc.creator.author | Mahgoub, Aya | |
dc.creator.author | Hagen, Cornelis W. | |
dc.creator.author | Tilset, Mats | |
cristin.unitcode | 185,15,17,0 | |
cristin.unitname | Senter for materialvitenskap og nanoteknologi | |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 1 | |
dc.identifier.cristin | 1929984 | |
dc.identifier.bibliographiccitation | info:ofi/fmt:kev:mtx:ctx&ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Beilstein Journal of Nanotechnology&rft.volume=12&rft.spage=257&rft.date=2021 | |
dc.identifier.jtitle | Beilstein Journal of Nanotechnology | |
dc.identifier.volume | 12 | |
dc.identifier.startpage | 257 | |
dc.identifier.endpage | 269 | |
dc.identifier.doi | https://doi.org/10.3762/bjnano.12.21 | |
dc.identifier.urn | URN:NBN:no-95217 | |
dc.type.document | Tidsskriftartikkel | |
dc.type.peerreviewed | Peer reviewed | |
dc.source.issn | 2190-4286 | |
dc.identifier.fulltext | Fulltext https://www.duo.uio.no/bitstream/handle/10852/92656/1/2190-4286-12-21.pdf | |
dc.type.version | PublishedVersion | |
dc.relation.project | NFR/226244/F50 | |
dc.relation.project | NFR/226244 | |