dc.date.accessioned | 2021-03-26T21:24:50Z | |
dc.date.available | 2021-03-26T21:24:50Z | |
dc.date.created | 2021-02-15T14:52:40Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Romagnoli, Carlo Sieng, Bora Amedjkouh, Mohamed . Kinetic relationship in parallel autocatalytic amplifications of pyridyl alkanol and chiral trigger pyrimidyl alkanol. Chirality. 2020, 32(9), 1143-1151 | |
dc.identifier.uri | http://hdl.handle.net/10852/85003 | |
dc.description.abstract | Experimental and kinetic analysis of a chemical system combines autocatalytic amplification of 2‐alkynyl‐5‐pyrimidyl alkanol 2 and 6‐alkynyl‐3‐pyridyl akanol 4 in which 2 acts as a chiral trigger and 4 being the subsequent autocatalyst. Starting from a very low initial ee, both alkanols are produced with high enantiopurity in one single cycle. This provides insight into a dual nonlinear amplification of chirality observed with amplifying trigger 2 and accelerated amplification of autocatalyst 4. These kinetic studies reveal a five‐fold magnitude superior amplification rates of 4 associated with trigger's enantiopurity at the outset. | |
dc.language | EN | |
dc.rights | Attribution 4.0 International | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.title | Kinetic relationship in parallel autocatalytic amplifications of pyridyl alkanol and chiral trigger pyrimidyl alkanol | |
dc.type | Journal article | |
dc.creator.author | Romagnoli, Carlo | |
dc.creator.author | Sieng, Bora | |
dc.creator.author | Amedjkouh, Mohamed | |
cristin.unitcode | 185,15,12,0 | |
cristin.unitname | Kjemisk institutt | |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 1 | |
dc.identifier.cristin | 1889990 | |
dc.identifier.bibliographiccitation | info:ofi/fmt:kev:mtx:ctx&ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chirality&rft.volume=32&rft.spage=1143&rft.date=2020 | |
dc.identifier.jtitle | Chirality | |
dc.identifier.volume | 32 | |
dc.identifier.issue | 9 | |
dc.identifier.startpage | 1143 | |
dc.identifier.endpage | 1151 | |
dc.identifier.doi | https://doi.org/10.1002/chir.23256 | |
dc.identifier.urn | URN:NBN:no-87695 | |
dc.type.document | Tidsskriftartikkel | |
dc.type.peerreviewed | Peer reviewed | |
dc.source.issn | 0899-0042 | |
dc.identifier.fulltext | Fulltext https://www.duo.uio.no/bitstream/handle/10852/85003/2/chir.23256.pdf | |
dc.type.version | PublishedVersion | |