dc.date.accessioned | 2018-02-08T15:23:14Z | |
dc.date.available | 2019-02-16T23:31:26Z | |
dc.date.created | 2017-03-09T18:30:16Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Kusakovskij, Jevgenij De Cooman, Hendrik Sagstuen, Einar Callens, Freddy J. Vrielinck, Henk . On the identity of the last known stable radical in X-irradiated sucrose. Chemical Physics Letters. 2017, 674, 6-10 | |
dc.identifier.uri | http://hdl.handle.net/10852/59964 | |
dc.description.abstract | Identification of radiation-induced radicals in relatively simple molecules is a prerequisite for the understanding of reaction pathways of the radiation chemistry of complex systems. Sucrose presents an additional practical interest as a versatile radiation dosimetric system. In this work, we present a periodic density functional theory study aimed to identify the fourth stable radical species in this carbohydrate. The proposed model is a fragment suspended in the lattice by hydrogen bonds with an unpaired electron at the original C5’ carbon of the fructose unit. It requires a double scission of the ring accompanied by substantial chemical and geometric reorganization. | en_US |
dc.language | EN | |
dc.publisher | Elsevier Science | |
dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/3.0/ | |
dc.title | On the identity of the last known stable radical in X-irradiated sucrose | en_US |
dc.type | Journal article | en_US |
dc.creator.author | Kusakovskij, Jevgenij | |
dc.creator.author | De Cooman, Hendrik | |
dc.creator.author | Sagstuen, Einar | |
dc.creator.author | Callens, Freddy J. | |
dc.creator.author | Vrielinck, Henk | |
cristin.unitcode | 185,15,4,50 | |
cristin.unitname | Biofysikk og medisinsk fysikk | |
cristin.ispublished | true | |
cristin.fulltext | postprint | |
cristin.qualitycode | 1 | |
dc.identifier.cristin | 1457079 | |
dc.identifier.bibliographiccitation | info:ofi/fmt:kev:mtx:ctx&ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical Physics Letters&rft.volume=674&rft.spage=6&rft.date=2017 | |
dc.identifier.jtitle | Chemical Physics Letters | |
dc.identifier.volume | 674 | |
dc.identifier.startpage | 6 | |
dc.identifier.endpage | 10 | |
dc.identifier.doi | http://dx.doi.org/10.1016/j.cplett.2017.02.032 | |
dc.identifier.urn | URN:NBN:no-62656 | |
dc.type.document | Tidsskriftartikkel | en_US |
dc.type.peerreviewed | Peer reviewed | |
dc.source.issn | 0009-2614 | |
dc.identifier.fulltext | Fulltext https://www.duo.uio.no/bitstream/handle/10852/59964/2/sucrose4p.pdf | |
dc.type.version | AcceptedVersion | |