Browsing Kjemisk institutt by Author "Holmsen, Marte Sofie Martinsen"

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  • Au(III) π-Allyl Complexes: Synthesis, Structure, Reactivity, and Catalytic Applications 
    Vesseur, David; Holmsen, Marte Sofie Martinsen; Bourissou, Didier (Journal article / Tidsskriftartikkel / PublishedVersion; Peer reviewed, 2023)
    Abstract π‐Allyl complexes of transition metals are key species in organometallic chemistry and homogeneous catalysis. Palladium(II) π‐allyl complexes in particular, have gained a lot of attention, but their isoelectronic ...
  • Cyclometalated (N,C) Au(III) Complexes: The Impact of Trans Effects on Their Synthesis, Structure, and Reactivity 
    Holmsen, Marte Sofie Martinsen; Nova Flores, Ainara; Tilset, Mats (Journal article / Tidsskriftartikkel / PublishedVersion; Peer reviewed, 2023)
    The early years of gold catalysis were dominated by Au(I) complexes and inorganic Au(III) salts. Thanks to the development of chelating ligands, more sophisticated Au(III) complexes can now be easily prepared and handled. ...
  • Energetics of key Au(iii)-substrate adducts relevant to catalytic hydroarylation of alkynes 
    Regnacq, Matthieu; Lesage, Denis; Holmsen, Marte Sofie Martinsen; Miqueu, Karinne; Bourissou, Didier; Gimbert, Yves (Journal article / Tidsskriftartikkel / PublishedVersion; Peer reviewed, 2023)
    (P,C)-cyclometalated Au(III) complexes have shown remarkable ability to catalyze the intermolecular hydroarylation of alkynes. Evidence of an outer-sphere mechanism has been provided in a previous study and is confirmed ...
  • Small-molecule activation at gold: synthesis and reactivity of cyclometalated Au(III) complexes 
    Holmsen, Marte Sofie Martinsen (Doctoral thesis / Doktoravhandling, 2019)
    The interest in organogold chemistry has increased rapidly during the last 20-30 years, and nowadays there are numerous research group across the world working with gold and its rich chemistry. Au(I) complexes have been ...
  • σ-Cyclopropyl to π-Allyl Rearrangement at AuIII 
    Holmsen, Marte Sofie Martinsen; Vesseur, David; García-Rodeja, Yago; Miqueu, Karinne; Bourissou, Didier (Journal article / Tidsskriftartikkel / PublishedVersion; Peer reviewed, 2023)
    Abstract The possibility for Au III σ‐cyclopropyl complexes to undergo ring‐opening and give π‐allyl complexes was interrogated. The transformation was first evidenced within (P,C)‐cyclometalated complexes, it occurs within ...