Browsing Kjemisk institutt by Author "Holmsen, Marte Sofie"

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  • A highly asymmetric gold(III) η3‐allyl complex 
    Holmsen, Marte Sofie; Nova, Ainara; Øien-Ødegaard, Sigurd; Heyn, Richard H.; Tilset, Mats (Journal article / Tidsskriftartikkel / PublishedVersion; Peer reviewed, 2020)
    A highly asymmetric AuIII η3‐allyl complex has been generated by treating Au(η1‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf2. The resulting η3‐allyl complex has been characterized by NMR spectroscopy and X‐ray ...
  • Synthesis, structure and dynamics of new metal N-heterocyclic carbene complexes 
    Holmsen, Marte Sofie (Master thesis / Masteroppgave, 2013)
    Metal complexes of N-heterocyclic carbenes are potential useful catalysts and are therefore of large interest. In this master thesis, it was attempted to synthesize several metal complexes bearing a new chelating N-heterocyclic ...
  • trans-Mutation at Gold(III): A mechanistic study of a catalytic acetylene functionalization via a double insertion pathway 
    Holmsen, Marte Sofie; Nova, Ainara; Balcells, David; Langseth, Eirin; Øien-Ødegaard, Sigurd; Heyn, Richard H.; Tilset, Mats; Laurenczy, Gábor (Journal article / Tidsskriftartikkel / SubmittedVersion, 2017)
    The Au(III) complex Au(tpy)(OAcF)2 (OAcF = OCOCF3; tpy = 2-(p-tolyl)pyridine) catalyzes the anti addition of trifluoroacetic acid (HOAcF) to acetylene to furnish vinyl trifluoroacetate. The Au(III) vinyl complex ...