Browsing Kjemisk institutt by Author "Bourissou, Didier"

Now showing items 1-3 of 3

  • Au(III) π-Allyl Complexes: Synthesis, Structure, Reactivity, and Catalytic Applications 
    Vesseur, David; Holmsen, Marte Sofie Martinsen; Bourissou, Didier (Journal article / Tidsskriftartikkel / PublishedVersion; Peer reviewed, 2023)
    Abstract π‐Allyl complexes of transition metals are key species in organometallic chemistry and homogeneous catalysis. Palladium(II) π‐allyl complexes in particular, have gained a lot of attention, but their isoelectronic ...
  • Energetics of key Au(iii)-substrate adducts relevant to catalytic hydroarylation of alkynes 
    Regnacq, Matthieu; Lesage, Denis; Holmsen, Marte Sofie Martinsen; Miqueu, Karinne; Bourissou, Didier; Gimbert, Yves (Journal article / Tidsskriftartikkel / PublishedVersion; Peer reviewed, 2023)
    (P,C)-cyclometalated Au(III) complexes have shown remarkable ability to catalyze the intermolecular hydroarylation of alkynes. Evidence of an outer-sphere mechanism has been provided in a previous study and is confirmed ...
  • σ-Cyclopropyl to π-Allyl Rearrangement at AuIII 
    Holmsen, Marte Sofie Martinsen; Vesseur, David; García-Rodeja, Yago; Miqueu, Karinne; Bourissou, Didier (Journal article / Tidsskriftartikkel / PublishedVersion; Peer reviewed, 2023)
    Abstract The possibility for Au III σ‐cyclopropyl complexes to undergo ring‐opening and give π‐allyl complexes was interrogated. The transformation was first evidenced within (P,C)‐cyclometalated complexes, it occurs within ...