dc.date.accessioned | 2015-03-26T15:09:32Z | |
dc.date.available | 2015-03-26T15:09:32Z | |
dc.date.created | 2015-02-08T10:42:07Z | |
dc.date.issued | 2014 | |
dc.identifier.citation | Gørbitz, Carl Henrik Qi, Lianglin Mai, Ngan Thi Kim Kristiansen, Håvard . Redetermined crystal structure of α-dl-methionine at 340 K. Acta Crystallographica Section E: Structure Reports Online. 2014, 70(11), 337-340 | |
dc.identifier.uri | http://hdl.handle.net/10852/43501 | |
dc.description.abstract | Two forms, α and β, are known for the racemic amino acid DL-methionine, C5H11NO2S. The phase transition between them, taking place around 326 K, is associated with sliding at the central interfaces of the hydrophobic regions in the crystal, leaving the hydrogen-bonding pattern unperturbed. For the high-temperature [alpha] phase, only a structure of rather low quality has been available [R factor = 0.118, no H-atom coordinates; Taniguchi et al. (1980). Bull. Chem. Soc. Jpn, 53, 803-804]. We here present accurate structural data for this polymorph [R(F) = 0.049], which are compared with other related amino acid structures with similar properties. We report for the first time that the side chain of this phase has a minor disorder component [occupancy 0.0491 (18)] with a gauche+ rather than a gauche- conformation for the N-C-C-C group. In the crystal of the title compound, N-H...O hydrogen bonds link the molecules into (100) sheets. | |
dc.language | EN | |
dc.language.iso | en | en_US |
dc.publisher | International Union of Crystallography | |
dc.rights | Attribution 2.0 UK: England & Wales | |
dc.rights.uri | http://creativecommons.org/licenses/by/2.0/uk/ | |
dc.title | Redetermined crystal structure of α-dl-methionine at 340 K | en_US |
dc.type | Journal article | en_US |
dc.creator.author | Gørbitz, Carl Henrik | |
dc.creator.author | Qi, Lianglin | |
dc.creator.author | Mai, Ngan Thi Kim | |
dc.creator.author | Kristiansen, Håvard | |
cristin.unitcode | 185,15,12,0 | |
cristin.unitname | Kjemisk institutt | |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 1 | |
dc.identifier.cristin | 1218455 | |
dc.identifier.bibliographiccitation | info:ofi/fmt:kev:mtx:ctx&ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Acta Crystallographica Section E: Structure Reports Online&rft.volume=70&rft.spage=337&rft.date=2014 | |
dc.identifier.jtitle | Acta Crystallographica Section E: Structure Reports Online | |
dc.identifier.volume | E70 | |
dc.identifier.startpage | 337 | |
dc.identifier.endpage | 340 | |
dc.identifier.doi | http://dx.doi.org/10.1107/S1600536814022211 | |
dc.identifier.urn | URN:NBN:no-47872 | |
dc.type.document | Tidsskriftartikkel | en_US |
dc.type.peerreviewed | Peer reviewed | |
dc.source.issn | 1600-5368 | |
dc.identifier.fulltext | Fulltext https://www.duo.uio.no/bitstream/handle/10852/43501/2/hb7288-gorbitz.pdf | |
dc.type.version | PublishedVersion | |