dc.date.accessioned | 2024-03-10T20:33:01Z | |
dc.date.available | 2024-03-10T20:33:01Z | |
dc.date.created | 2023-10-12T08:47:26Z | |
dc.date.issued | 2023 | |
dc.identifier.citation | Lara Garnica, Rebeca Rama, Raquel J. Chambrier, Isabelle Agonigi, Gabriele Hughes, David L. Lalinde, Elena Bochmann, Manfred Fernandez-Cestau, Julio . Luminescent Au(III)-M(I) (M = Cu, Ag) Aggregates Based on Dicyclometalated Bis(alkynyl) Gold Anions. Inorganic Chemistry. 2023, 62(32), 12683-12696 | |
dc.identifier.uri | http://hdl.handle.net/10852/109446 | |
dc.description.abstract | The syntheses and structures of a series of complexes based on the C∧C-chelated Au(III) unit (C∧C = 4,4′-bis(t-butyl) 2,2′-biphenyl-1,1′-diyl) are reported, namely, [{(C∧C)Au(C≡CtBu)2}2M2], (C∧C)Au(C≡CR)(C≡NXyl), and [{(C∧C)Au(C≡CR)2}{M(C≡NXyl)}] (M = Ag, Cu; R = tBu, C6H4tBu-4, C6H4OMe-4; Xyl = 3,5-Me2C6H3). The X-ray structures reveal a broad range of dispositions determined by the different coordination modes of Ag(I) or Cu(I). The complexes are bright photoemitters in the solid state and in poly(methyl methacrylate) (PMMA) films. The photoluminescence is dominated by 3IL(C∧C) transitions, with indirect effects from the rest of the molecules, as supported by theoretical calculations. This work opens up the possibility of accessing Au(III) carbon-rich anions to construct photoluminescent aggregates. | |
dc.language | EN | |
dc.publisher | ACS Publications | |
dc.rights | Attribution 4.0 International | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.title | Luminescent Au(III)-M(I) (M = Cu, Ag) Aggregates Based on Dicyclometalated Bis(alkynyl) Gold Anions | |
dc.title.alternative | ENEngelskEnglishLuminescent Au(III)-M(I) (M = Cu, Ag) Aggregates Based on Dicyclometalated Bis(alkynyl) Gold Anions | |
dc.type | Journal article | |
dc.creator.author | Lara Garnica, Rebeca | |
dc.creator.author | Rama, Raquel J. | |
dc.creator.author | Chambrier, Isabelle | |
dc.creator.author | Agonigi, Gabriele | |
dc.creator.author | Hughes, David L. | |
dc.creator.author | Lalinde, Elena | |
dc.creator.author | Bochmann, Manfred | |
dc.creator.author | Fernandez-Cestau, Julio | |
cristin.unitcode | 185,15,17,10 | |
cristin.unitname | Senter for Materialvitenskap og Nanoteknologi kjemi | |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 2 | |
dc.identifier.cristin | 2183954 | |
dc.identifier.bibliographiccitation | info:ofi/fmt:kev:mtx:ctx&ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganic Chemistry&rft.volume=62&rft.spage=12683&rft.date=2023 | |
dc.identifier.jtitle | Inorganic Chemistry | |
dc.identifier.volume | 62 | |
dc.identifier.issue | 32 | |
dc.identifier.startpage | 12683 | |
dc.identifier.endpage | 12696 | |
dc.identifier.doi | https://doi.org/10.1021/acs.inorgchem.3c00870 | |
dc.type.document | Tidsskriftartikkel | |
dc.type.peerreviewed | Peer reviewed | |
dc.source.issn | 0020-1669 | |
dc.type.version | PublishedVersion | |
dc.relation.project | EU/338944 | |
dc.relation.project | EU/101061858 | |