dc.date.accessioned | 2024-03-05T21:04:35Z | |
dc.date.available | 2024-03-05T21:04:35Z | |
dc.date.created | 2023-07-26T11:00:07Z | |
dc.date.issued | 2023 | |
dc.identifier.citation | Pintea, Maria Mason, Nigel Peiró-Franch, Anna Clark, Ewan Samanta, Kushal Glessi, Cristiano Schmidtke, Inga Lena Luxford, Thomas . Dissociative electron attachment to gold(I)-based compounds: 4,5-dichloro-1,3-diethyl-imidazolylidene trifluoromethyl gold(I). Frontiers in Chemistry. 2023, 11 | |
dc.identifier.uri | http://hdl.handle.net/10852/109195 | |
dc.description.abstract | With the use of proton-NMR and powder XRD (XRPD) studies, the suitability of specific Au-focused electron beam induced deposition (FEBID) precursors has been investigated with low electron energy, structure, excited states and resonances, structural crystal modifications, flexibility, and vaporization level. 4,5-Dichloro-1,3-diethyl-imidazolylidene trifluoromethyl gold(I) is a compound that is a uniquely designed precursor to meet the needs of focused electron beam-induced deposition at the nanostructure level, which proves its capability in creating high purity structures, and its growing importance in other AuIm x and AuCl n B (where x and n are the number of radicals, B = CH, CH 3 , or Br) compounds in the radiation cancer therapy increases the efforts to design more suitable bonds in processes of SEM (scanning electron microscopy) deposition and in gas-phase studies. The investigation performed of its powder shape using the XRPD XPERT 3 panalytical diffractometer based on CoK α lines shows changes to its structure with change in temperature, level of vacuum, and light; the sensitivity of this compound makes it highly interesting in particular to the radiation research. Used in FEBID, though its smaller number of C, H, and O atoms has lower levels of C contamination in the structures and on the surface, it replaces these bonds with C–Cl and C–N bonds that have lower bond-breaking energy. However, it still needs an extra purification step in the deposition process, either H 2 O, O 2 , or H jets. | |
dc.language | EN | |
dc.rights | Attribution 4.0 International | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.title | Dissociative electron attachment to gold(I)-based compounds: 4,5-dichloro-1,3-diethyl-imidazolylidene trifluoromethyl gold(I) | |
dc.title.alternative | ENEngelskEnglishDissociative electron attachment to gold(I)-based compounds: 4,5-dichloro-1,3-diethyl-imidazolylidene trifluoromethyl gold(I) | |
dc.type | Journal article | |
dc.creator.author | Pintea, Maria | |
dc.creator.author | Mason, Nigel | |
dc.creator.author | Peiró-Franch, Anna | |
dc.creator.author | Clark, Ewan | |
dc.creator.author | Samanta, Kushal | |
dc.creator.author | Glessi, Cristiano | |
dc.creator.author | Schmidtke, Inga Lena | |
dc.creator.author | Luxford, Thomas | |
cristin.unitcode | 185,15,12,0 | |
cristin.unitname | Kjemisk institutt | |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 1 | |
dc.identifier.cristin | 2163623 | |
dc.identifier.bibliographiccitation | info:ofi/fmt:kev:mtx:ctx&ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Frontiers in Chemistry&rft.volume=11&rft.spage=&rft.date=2023 | |
dc.identifier.jtitle | Frontiers in Chemistry | |
dc.identifier.volume | 11 | |
dc.identifier.pagecount | 0 | |
dc.identifier.doi | https://doi.org/10.3389/fchem.2023.1028008 | |
dc.type.document | Tidsskriftartikkel | |
dc.type.peerreviewed | Peer reviewed | |
dc.source.issn | 2296-2646 | |
dc.type.version | PublishedVersion | |
cristin.articleid | 1288 | |