Selective Functionalization of Arene C(sp2)-H Bonds by Gold Catalysis: The Role of Carbene Substituents

dc.date.accessioned	2023-02-21T18:06:04Z
dc.date.available	2023-02-21T18:06:04Z
dc.date.created	2022-09-14T11:31:33Z
dc.date.issued	2022
dc.identifier.citation	Pizarro, Juan Diego Schmidtke, Inga Nova, Ainara Fructos, Manuel R. Pérez, Pedro J. . Selective Functionalization of Arene C(sp2)-H Bonds by Gold Catalysis: The Role of Carbene Substituents. ACS Catalysis. 2022, 12(12), 6851-6856
dc.identifier.uri	http://hdl.handle.net/10852/100225
dc.description.abstract	The complete regioselective incorporation of carbene units to nonactivated arene rings has been achieved employing gold(I) catalysts bearing alkoxydiaminophosphine ligands, with readily available, nonelaborated ethyl 2-phenyldiazoacetate as the carbene source. These results are in contrast with the scarce precedents which required highly elaborated diazo substrates. Density functional theory (DFT) calculations have revealed the important role of the R group in the C(R)CO2Et fragment, which dramatically affects the energy profile of this transformation.
dc.language	EN
dc.rights	Attribution 4.0 International
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/
dc.title	Selective Functionalization of Arene C(sp2)-H Bonds by Gold Catalysis: The Role of Carbene Substituents
dc.title.alternative	ENEngelskEnglishSelective Functionalization of Arene C(sp2)-H Bonds by Gold Catalysis: The Role of Carbene Substituents
dc.type	Journal article
dc.creator.author	Pizarro, Juan Diego
dc.creator.author	Schmidtke, Inga
dc.creator.author	Nova, Ainara
dc.creator.author	Fructos, Manuel R.
dc.creator.author	Pérez, Pedro J.
cristin.unitcode	185,15,17,10
cristin.unitname	Senter for Materialvitenskap og Nanoteknologi kjemi
cristin.ispublished	true
cristin.fulltext	original
cristin.qualitycode	2
dc.identifier.cristin	2051579
dc.identifier.bibliographiccitation	info:ofi/fmt:kev:mtx:ctx&ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=ACS Catalysis&rft.volume=12&rft.spage=6851&rft.date=2022
dc.identifier.jtitle	ACS Catalysis
dc.identifier.volume	12
dc.identifier.issue	12
dc.identifier.startpage	6851
dc.identifier.endpage	6856
dc.identifier.doi	https://doi.org/10.1021/acscatal.2c01713
dc.type.document	Tidsskriftartikkel
dc.type.peerreviewed	Peer reviewed
dc.source.issn	2155-5435
dc.type.version	PublishedVersion
dc.relation.project	NFR/314321
dc.relation.project	NFR/262695
dc.relation.project	SIGMA2/nn4654k